The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / Cl2O3 / Harwood(1995)_223K_220-330nm

DATAFILE: Cl2O3_Harwood(1995)_223K_220-330nm.txt
NAME: dichlorine trioxide, chlorine sesquioxide, chlorine chlorate
FORMULA: Cl2O3
AUTHOR(YEAR): Harwood(1995)
T: 223K
λ: 220-330nm
BIBLIOGRAPHY: M.H. Harwood, D.M. Rowley, R.A. Freshwater, R.A. Cox, and R.L. Jones, "A spectroscopic study of Cl2O3", J. Chem. Soc. Faraday Trans. 91, 3027-3032 (1995); DOI: 10.1039/FT9959103027
COMMENTS: Structure: ClOClO2

Measurements using a flash photolysis-UV absorption spectroscopy system; spectral resolution 4.1 nm (FWHM)

Cl2O3 was generated in the reaction between ClO and OClO following the partial photolysis of OClO

The data are averages over 5-nm intervals

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